Preheat the oven to 170°C and prepare the pan by greasing it well with butter and lightly coating it with flour so the cake releases easily.
In a bowl, combine the flour, cocoa powder, coffee powder, baking powder, baking soda, and salt.
Add both sugars along with the buttermilk, egg, oil, and vanilla, then whisk until the mixture is smooth and cohesive.
Slowly pour in the hot water and whisk again until fully incorporated. Don’t worry if the batter seems runny, that’s exactly how it should be.
Transfer the batter to the prepared pan and bake for 25-30 minutes, until a skewer inserted into the center comes out clean. Allow the cake to cool completely before assembling or decorating.